Payooner is a Mastercard-supported debit card. It was intended for online transactions. Paypal also accepts it in verifying your account. You cannot just ask and get it from Payoneer, though. You need to have a third party to have it. Usually these are trusted sites with affliate programs. And thus, I'll make it easier for you to get your Free Payoneer Debit Card by registering to a site that I know. The site is called friendfinder. It is social networking/online dating site like Myspace and Facebook. It has an affiliate program which allows you to choose for a payment processor which includes a Payoneer Debit Card. Here is a really short step of getting your Free Payoneer Debit Card.
 
1. Got to the site's homepage friendfinder

2. Locate the affiliate button. A button that says 'Affiliate' or 'Affiliate Program.' The may change their page layout so just try to explore the page.
 
3. After clicking, sign up.

4. Click Option 1

5. For the phone number, use the format they are requesting. It’s like this (your country id)(your city code)(your number).

6. In 'Use Passporte' item , choose NO. In 'Your comment' item, just put anything. Accept the agreement, etc, etc, and click Submit.

7. After which, find 'blue' words, click Account Information, choose 'Click here to update your information' and finally click on 'Payoneer: Signup to be paid by Prepaid MasterCard®'.You will be directed to a FriendFinder page hosted by Payoneer, where you can sign up for a card.

8. Finish the final sign up process and you will need to wait for 2-20 working days + delivery days